Tiny Particles, Big Surprises: The Unexpected Complexity of Catalysts

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Tiny Particles, Big Surprises: The Unexpected Complexity of Catalysts
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Tiny Particles, Big Surprises: The Unexpected Complexity of Catalysts — At TU Wien, scientists use |

Catalysis under the microscope. TU Wien researchers using advanced microscopy techniques have discovered intricate complexities in catalyst behavior. The study found that factors such as particle size, support material nature, temperature, and reactant pressures play crucial roles in catalytic activity. The discovery of significant local variation within individual catalyst particles will inform future research into more complex processes and the development of improved catalysts.

Catalysts composed of tiny metal particles play an important role in many areas of technology – from fuel cells to the production of synthetic fuels for energy storage. The exact behavior of catalysts depends, however, on many fine details and their interplay is often difficult to understand. Even when preparing exactly the same catalyst twice, it often occurs that these two will differ in minute aspects and therefore behave very differently chemically.

In doing so, it appeared that even relatively “simple” catalytic systems were more complex than expected. For example, it is not only the size of the employed metal particles or the chemical nature of the support material that defines the catalytic properties. Even within a single metal particle, different scenarios can prevail on the micrometer scale. In combination with numeric simulations, the behavior of different catalysts could then be explained and correctly predicted.

“The catalyst is made from supported rhodium particles, but it does not behave like a uniform object which can be described by a few simple parameters, as often tried in the past,” highlights Günther Rupprechter. “It soon became clear, that the catalytic behavior strongly varies at different catalyst locations. A given area on a given rhodium particle may be catalytically active, whereas another one, just micrometers away, may be catalytically inactive.

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